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Chemistry Of Hydrocarbon Compounds > Aromatic Compound Synthesis > By Condensation Of Entire Molecules Or Entire Hydrocarbyl Moieties Thereof, E.g., Alkylation, Etc. > Using Metal, Metal Oxide, Or Hydroxide Catalyst

Using Metal, Metal Oxide, Or Hydroxide Catalyst

Using Metal, Metal Oxide, Or Hydroxide Catalyst patent applications listed are from June 2005 to current and include Date, Patent Application Number, Patent Title, Patent Abstract summary and are linked to the corresponding patent application page.

12/21/06 - 20060287562 - Process for the production of phenyl alkanes operating in a moving bed
A process for the production of phenyl alkanes by catalytic alkylation on a solid acid catalyst employs at least one moving-bed reactor. This process comprises a catalytic alkylation stage of an aromatic compound by at least one olefin that has 9 to 16 carbon atoms per molecule, combined with a ...

11/30/06 - 20060270881 - Multi-component molecular sieve catalyst compositions and their use in aromatics reactions
The invention relates to a process for producing alkylated aromatic hydrocarbons, preferably with an oxygen or sulfur containing alkylating agent, in the presence of a multi-component molecular sieve catalyst composition that includes a molecular sieve and an active metal oxide. The invention is also directed to methods of making and ...

11/23/06 - 20060264685 - Process for producing para-xylene
A process for producing para-xylene by the selective methylation of toluene comprising contacting a reactant mixture comprising toluene, methanol and added water, with an oxide modified ZSM-5 zeolite catalyst in a flow reactor in conditions selected to limit coke formation on the catalyst and at a contact time, between reactant ...

11/02/06 - 20060247480 - Hydrocarbon conversion processes using a catalyst comprising a uzm-8hs composition
Hydrocarbon conversion processes using a new family of zeolites identified as UZM-8HS are described. The UZM-8HS zeolite are derived from UZM-8 zeolites by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8HS zeolites have unique x-ray diffraction patterns. These zeolites can be used in alkylation of aromatics, ...

11/02/06 - 20060247479 - Ethyl benzene from refinery grade feedstocks
“Chemical grade” ethyl benzene is synthesized by the alkylation of the benzene which is contained in the reformate stream of a refinery with the ethylene in FCC (fluid catalytic cracker) off gas. The reformate stream is not hydrogenated prior to the alkylation. The alkylation reaction takes place in a fixed ...

10/12/06 - 20060229479 - Process for the production of alkylbenzene
A process for the production of alkylbenzene includes the steps of introducing benzene and an olefin feed into a first alkylation reaction zone in the presence of a first alkylation catalyst under first alkylation reaction conditions to produce alkylbenzene and a vapor containing unconverted olefin; absorbing the unconverted olefin into ...

10/05/06 - 20060224031 - Alkylation process using uzm-8 zeolite
A process for the alkylation of aromatics with olefins using a solid catalyst bed containing UZM-8 zeolite is disclosed. A polyalkylated aromatic is passed to the catalyst bed to reduce the concentration of the olefin at alkylation conditions. A portion of the effluent recovered from the catalyst bed may be ...

10/05/06 - 20060224030 - Process for the production of phenylalkanes that use a zeolitic catalyst that is based on silica-alumina
An alkylating process for the production of at least one of 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound with a feedstock containing at least one olefin comprising at least 9 carbon atoms per molecule, in the presence of a catalyst comprising at least one substrate ...

09/21/06 - 20060211901 - Process for the co-production of cumene and secondary butyl benzene
Cumene and secondary butyl benzene are produced simultaneously in a distillation column reactor by feeding propylene, butylene and benzene to the reactor. Unreacted benzene is removed as overheads and cumene and secondary butyl benzene are removed as products. The catalysts used are acid cation exchange resins, zeolites, particularly beta zeolite. ...

08/31/06 - 20060194999 - Gasoline production by olefin polymerization
Solid phosphoric acid (SPA) olefin oligomerization process units may be converted to operation with a more environmentally favorable solid catalyst. The SPA units in which a light olefin feed is oligomerized to form gasoline boiling range hydrocarbon product, is converted unit to operation with a molecular sieve based olefin oligomerization ...

08/31/06 - 20060194998 - Process for making high octane gasoline with reduced benzene content
Solid phosphoric acid (SPA) olefin oligomerization process units may be converted to operation with a more environmentally favorable solid catalyst. The SPA units in which a light olefin feed is oligomerized to form gasoline boiling range hydrocarbon product, is converted unit to operation with a molecular sieve based olefin oligomerization ...

08/31/06 - 20060194997 - Vapor phase aromatics alkylation process
A process for the production of high octane number gasoline from light refinery olefins and benzene-containing aromatic streams such as reformate. The process achieves good utilization of both the ethylene and the propylene present in the mixed olefin feed from the unsaturated gas plant while reducing gasoline benzene levels. The ...

08/31/06 - 20060194996 - Liquid phase aromatics alkylation process
A process for the production of high octane number gasoline from light refinery olefins and benzene-containing aromatic streams such as reformate. Light olefins including ethylene and propylene are extracted from refinery off-gases, typically from the catalytic cracking unit, into a light aromatic stream such as reformate containing benzene and other ...

08/31/06 - 20060194995 - Gasoline production by olefin polymerization with aromatics alkylation
A process for the production of high octane number gasoline from light refinery olefins, typically from the catalytic cracking unit, and benzene-containing aromatic streams such as reformate. A portion of the light olefins including ethylene and propylene is polymerized to form a gasoline boiling range product and another portion is ...

08/31/06 - 20060194994 - Critical phase alkylation process
A process for the production of ethylbenzene by the ethylation of benzene in the critical phase in a reaction zone containing a molecular sieve aromatic alkylation catalyst comprising cerium-promoted zeolite beta. A polyethylbenzene is supplied into the reaction zone and into contact with the cerium-promoted zeolite beta having a silica/alumina ...

08/10/06 - 20060178544 - Selective alkylation of aromatic hydrocarbons
A method for increasing selectivity of alkylation to monoalkylation comprising: providing a feedstream consisting essentially of alkylating agent and a stoichiometric excess of benzene, the alkylating agent consisting essentially of a molar blend of propylene and one or more linear butene(s); and, contacting the feedstream with a catalytically effective amount ...

08/03/06 - 20060173225 - Process for the production of para-diethylbenzene
The present invention relates to a process for the selective production of para-diethyl benzene from a mixed aromatic feedstock containing ethyl benzene and at least one other aromatic compound selected from benzene, alkylated benzene having alkyl group with carbon number 1 to 6, mono-alkyl aromatics, dialkyl aromatics, trialkyl aromatics, tetraalkyl ...

07/06/06 - 20060149104 - Manufacture of xylenes from reformate
A process is provided for the production of xylenes from reformate. The process is carried out by methylating the benzene, toluene, or both present in the reformate to produce a resulting product having a higher xylenes content than the reformate. Greater than equilibrium amounts of para-xylene can be produced by ...

06/01/06 - 20060116539 - Use of monolith catalyst to prepare ethylbenzene
Disclosed is an alkylation reactor for preparing ethylbenzene. The reactor comprises a monolith catalyst system that includes a monolith support impregnated or co-formed with a catalyst suitable to catalyze the alkylation of benzene with ethylene. The catalyst may be selected from, for example, zeolites such as beta zeolite and MCM-22 ...

05/25/06 - 20060111597 - Alkylation and catalyst regenerative process
A process for the regeneration of a deactivated zeolite beta catalyst such as rare earth promoted zeolite beta catalyst deactivated in the course of an aromatic alkylation reaction. A zeolite beta conversion catalyst deactivated with the deposition of coke is heated to a temperature in excess of 300° C. in ...

02/16/06 - 20060036120 - Porous crystalline material (zeolite itq-24), preparation method thereof and use of same in the catalytic conversion of organic compounds
The invention relates to a porous crystalline material (ITQ-24), the preparation method thereof and the use of same in the catalytic conversion of organic compounds. More specifically, the invention relates to a synthetic porous crystalline material which is characterised in that it is formed by tetrahedrally coordinated atoms which are ...

01/26/06 - 20060020154 - Reduction of the bromine index of linear alkylbenzenes
In a process for reducing the Bromine Index of a feed containing a linear alkylbenzene and bromine-reactive olefinic hydrocarbon contaminants, the feed is contacted under conditions effective to remove bromine-reactive olefinic hydrocarbon contaminants with a catalyst comprising zeolite Y catalyst having an alpha value of about 2 to about 30. ...

01/12/06 - 20060009669 - Mordenite zeolite alkylation catalyst
The present invention is directed to a mordenite zeolite catalyst having a controlled macropore structure. The present invention is also directed to a mordenite zeolite catalyst composite and a process for preparing the catalyst composite. The catalyst composite exhibits reduced deactivation rates during the alkylation process, thereby increasing the life ...

01/05/06 - 20060004238 - Critical phase alkylation process
A process for the production of ethylbenzene by the ethylation of benzene in the critical phase over a molecular sieve aromatic alkylation catalyst comprising cerium-promoted zeolite beta. An aromatic feedstock having a benzene content of at least 90 wt. % is supplied into a reaction zone and into contact with ...

12/15/05 - 20050277795 - Preparation of alkyl-aromatic products
A method of modifying a ZSM-5-type zeolite catalyst to increase selectivity of the catalyst for para-isomers in aromatic alkylation reactions is provided. The method includes contacting a ZSM-5-type zeolite catalyst with a fluoride-containing compound. The fluoride-containing zeolite catalyst can be used in aromatic alkylation to provide di-alkyl aromatic products. A ...

11/10/05 - 20050250970 - Zeolite y alkylation catalysts
The present invention is directed to a zeolite Y catalyst having a controlled macropore structure. The present invention is also directed to a zeolite Y catalyst composite and a process for preparing the catalyst composite. The catalyst composite exhibits reduced deactivation rates during the alkylation process, thereby increasing the life ...

10/27/05 - 20050240070 - Zeolite catalyst and method
A catalyst is formed from a phosphorus-containing ZSM-5-type zeolite. The ZSM-5-type zeolite has a silica/alumina molar ratio of at least 200. The phosphorus-containing ZSM-5-type zeolite also has a phosphorus content of at least 8% by weight of zeolite and has multiple phosphorus species exhibited by at least two 31P MAS ...

09/22/05 - 20050209494 - Method of preparing an alkyl aromatic product
A method of modifying a zeolite catalyst to increase selectivity of the catalyst is achieved by dissolving alumina in a phosphorus-containing acid solution, and treating the zeolite catalyst with the dissolved alumina solution. A method of preparing an aromatic product, such as a xylene product, is also achieved by contacting ...

09/22/05 - 20050209493 - Aromatics alkylation
The present invention provides a process for producing an alkylaromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under alkylation conditions in the presence of a alkylation catalyst comprising phosphorus and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the ...

09/22/05 - 20050209492 - Toluene methylation process with increased methanol selectivity
A method of converting methanol to a xylene product is achieved by providing a reactor containing a non-steamed, phosphorus-treated ZSM-5-type zeolite catalyst. The catalyst is contacted with a toluene/methanol feed under reactor conditions suitable for the methylation of toluene. Water cofeed is introduced into the reactor during the methylation reaction ...

09/15/05 - 20050203323 - Mordenite zeolite alkylation catalysts
The present invention is directed to a mordenite zeolite catalyst having a controlled macropore structure. The present invention is also directed to a mordenite zeolite catalyst composite and a process for preparing the catalyst composite. The catalyst composite exhibits reduced deactivation rates during the alkylation process, thereby increasing the life ...

09/15/05 - 20050203322 - Zeolite y alkylation catalysts
The present invention is directed to a zeolite Y catalyst having a controlled macropore structure. The present invention is also directed to a zeolite Y catalyst composite and a process for preparing the catalyst composite. The catalyst composite exhibits reduced deactivation rates during the alkylation process, thereby increasing the life ...

09/08/05 - 20050197517 - Process for preparing short chain alkyl aromatic compounds
A process for producing alkyl aromatic compounds which comprises contacting at least one aromatic compound with at least one alkylating agent or transalkylating agent possessing at least one aliphatic group having from 1 to 5 carbon atoms under alkylation or transalkylation reaction conditions and in the presence of an alkylation ...

09/01/05 - 20050192469 - Zeolite catalyst for the alkylation of aromatic compounds with olefins, alcohols or polyalkylated aromatic compounds
The invention relates to a method of preparing an alkylated aromatic compound. The inventive method is characterized in that it comprises an alkylation reaction of an aromatic compound with an alkylating agent which is selected from an olefin, an alcohol and a polyalkylated aromatic compound, in the presence of a ...

08/25/05 - 20050187416 - Process for producing cumene
A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than ...

08/11/05 - 20050177017 - Process for the production of phenylalkanes that use a catalyst based on silicated alumina
The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the ...

07/28/05 - 20050165264 - Preparation of alkylaromatic hydrocarbons and alkylaryl sulfonates
wherein n is greater than or equal to 10, the mono-olefin oligomers comprising at least 20 percent by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. ...

07/14/05 - 20050154243 - Process for benzene alkylation and transalkylation of polyalkylated aromatics over improved zeolite beta catalyst
An aromatic alkylation process includes contacting an aromatic compound with an alkylating agent in the presence of a zeolite beta in a reaction zone under alkylation reaction conditions, wherein said zeolite beta is a high performance zeolite beta possessing a ratio of strong acid sites/weak acid sites greater than 1. ...

07/14/05 - 20050154242 - Aromatic alkylation catalyst and method
A catalyst for use in aromatic alkylation, such as toluene alkylation with methanol, is comprised of a zeolite with pore size from about 5.0 to about 7.0 Å containing a hydrogenating metal. The catalyst may be used in preparing an alkyl aromatic product by providing the catalyst within a reactor. ...

06/30/05 - 20050143613 - Process for aromatic alkylation
This invention relates to a process for the selective alkylation of toluene and/or benzene with an oxygen-containing alkylation agent. In particular, the process uses a selectivated molecular sieve which has been modified by the addition of a hydrogenation component, wherein at least one of the following conditions is met: (a) ...

06/23/05 - 20050137437 - Continuous preparation of 4,4'-diisopropylbiphenyl
A continuous flow process has been discovered for the highly selective isopropylation of biphenyl to 4,4′-diisopropylbiphenyl. Thus biphenyl and propene in decalin are passed through a solid zeolite catalyst bed contained in a flow reactor at moderate temperature (220° C.) and pressure (10-30 atm) together with a continuous stream of ...

06/09/05 - 20050124837 - Preparation of alkenylaromatic compounds
A process for preparing alkenylaromatic compounds by reacting alkylaromatic compounds in the presence of steam and natural gas or methane over a suitable catalyst at a temperature of from 400 to 800° C. and a pressure of from 0.01 to 10 bar, wherein the molar ratio of steam to alkylaromatic ...



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