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07/05/07 - USPTO Class 062 |  45 views | #20070151291 | Prev - Next | About this Page  062 rss/xml feed  monitor keywords

Method and installation for producing carbon monoxide by cryogenic distillation

USPTO Application #: 20070151291
Title: Method and installation for producing carbon monoxide by cryogenic distillation
Abstract: The invention relates to a method for producing carbon monoxide by cryogenic distillation. Said method comprises the following steps: a gaseous mixture (1) containing carbon monoxide, hydrogen and nitrogen is cooled and partially condensed to produce a cooled and partially condensed gaseous mixture; the cooled and partially condensed gaseous mixture (5) is separated in order to produce a gas enriched with hydrogen and a liquid enriched with carbon monoxide (11); a flow of the liquid enriched with carbon monoxide is sent to a product stripper (17) in order to produce hydrogen-depleted liquid carbon monoxide (19) and hydrogen-enriched gaseous carbon monoxide (RSD); a flow of the hydrogen-depleted carbon monoxide is sent to a first intermediate level of a distillation column (23); a liquid flow enriched with methane (27) compared to the flow supplied to the distillation column is drawn off from the bottom of the distillation column; a flow (29) enriched with carbon monoxide is drawn off at a second intermediate point above the first intermediate point; and a flow (RSDN2) enriched with nitrogen and optionally hydrogen compared to the flow supplied to the distillation column is drawn off from the top of the distillation column.
(end of abstract)
Agent: Air Liquide Intellectual Property - Houston, TX, US
Inventor: Daniele Fauroux
USPTO Applicaton #: 20070151291 - Class: 062617000 (USPTO)

Related Patent Categories: Refrigeration, Cryogenic Treatment Of Gas Or Gas Mixture, Separation Of Gas Mixture
The Patent Description & Claims data below is from USPTO Patent Application 20070151291.
Brief Patent Description - Full Patent Description - Patent Application Claims  monitor keywords

[0001] The present invention relates to a method and an installation for producing carbon monoxide by cryogenic distillation.

[0002] The synthesis gas produced by partial oxidation or by reforming often contains a percentage of nitrogen.

[0003] All the percentages mentioned are mole percentages.

[0004] It is known to reduce the percentage of nitrogen in the carbon monoxide produced by using a nitrogen and carbon monoxide separating column (EP-A-928936).

[0005] It is one object of the present invention to provide a cryogenic separation installation for producing carbon monoxide substantially containing no nitrogen using fewer columns than the installations of the prior art.

[0006] According to one object of the present invention, a method is provided for producing carbon monoxide by cryogenic distillation comprising the following steps:

[0007] i) a gas mixture containing carbon monoxide, hydrogen and nitrogen is cooled and partially condensed to produce a cooled and partially condensed gas mixture

[0008] ii) the cooled and partially condensed gas mixture is separated to produce a hydrogen-enriched gas and a carbon monoxide-enriched liquid

[0009] iii) a stream of the carbon monoxide-enriched liquid is sent to a stripping column to produce hydrogen-free liquid carbon monoxide and hydrogen-enriched carbon monoxide gas

[0010] iv) a stream of the hydrogen-free carbon monoxide is sent to a first intermediate level of a distillation column

[0011] v) a liquid stream, richer in methane compared to the stream feeding to the distillation column, is withdrawn from the bottom of the distillation column

[0012] vi) a carbon monoxide-rich stream is withdrawn from a second intermediate point, the second intermediate point being above the first intermediate point

[0013] vii) a stream, enriched with nitrogen and optionally hydrogen compared to the stream feeding to the distillation column, is withdrawn from the top of the distillation column

[0014] Optionally: [0015] the carbon monoxide-rich stream withdrawn from the distillation column is a liquid stream; [0016] a carbon monoxide cycle cools the top of the distillation column and/or heats the bottom of the distillation column and/or heats the bottom of the stripping column; [0017] cycle carbon monoxide is expanded in a turbine.

[0018] According to a further object of the invention, an installation is provided for producing carbon monoxide by cryogenic distillation comprising:

[0019] a) a heat exchanger for cooling and partially condensing a gas mixture containing carbon monoxide, hydrogen and nitrogen to produce a cooled and partially condensed gas mixture

[0020] b) a separator for separating the cooled and partially condensed gas mixture to produce a hydrogen-enriched gas and a carbon monoxide-enriched liquid

[0021] c) means for conveying the cooled and partially condensed gas mixture from the heat exchanger to the separator

[0022] d) a stripping column and means for conveying at least part of the carbon monoxide-enriched liquid thereto

[0023] e) means for withdrawing a hydrogen-enriched gas from the top of the stripping column and means for withdrawing a hydrogen-free liquid from the bottom of the stripping column

[0024] f) a distillation column, means for sending a stream of the hydrogen-free liquid to a first intermediate point of the distillation column, means for withdrawing a bottom liquid from the distillation column, means for withdrawing an overhead gas from the distillation column and means for withdrawing an intermediate fluid at a second intermediate point of the distillation column, the second intermediate point being above the first intermediate point.

[0025] Optionally: [0026] the distillation column has a top condenser and/or a bottom reboiler; [0027] the stripping column has a bottom reboiler; [0028] the column (columns) is (are) heated and/or cooled using a carbon monoxide gas cycle.

[0029] The invention is described in greater detail with reference to the single FIGURE.

[0030] In the FIGURE, a synthesis gas 1 containing 40% hydrogen, 58% carbon monoxide, 0.1% methane, 0.5% nitrogen and 1.3% argon.

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