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  Fiberglass nonwoven binderUSPTO Application #: 20060111002Title: Fiberglass nonwoven binder Abstract: The present invention relates to a nonwoven binder composition containing an aqueous solution of a copolymer binder having both an acid functionality and hydroxyl or amine functionality. The binder is especially useful as a binder for fiberglass fibers, to produce a fiberglass mat that is strongly bound, yet flexible. (end of abstract) Agent: National Starch And Chemical Company - Bridgewater, NJ, US Inventor: Klein A. Rodrigues USPTO Applicaton #: 20060111002 - Class: 442327000 (USPTO) Related Patent Categories: Fabric (woven, Knitted, Or Nonwoven Textile Or Cloth, Etc.), Nonwoven Fabric (i.e., Nonwoven Strand Or Fiber Material) The Patent Description & Claims data below is from USPTO Patent Application 20060111002. Brief Patent Description - Full Patent Description - Patent Application Claims
CROSS-REFERENCE TO RELATED APPLICATIONS [0001] The present application is a continuation of U.S. application Ser. No. 10/283,406, filed 29 Oct. 2002. FIELD OF THE INVENTION [0002] The invention relates to a non-woven binder composition containing a copolymer having both an acid and hydroxyl or amine functionality. The binder composition is especially useful for binding mineral fiber, and particularly as a fiberglass binder. The binder composition provides a strong, yet flexible bond that allows a compressed fiberglass mat to easily expand once the compression is released. BACKGROUND OF THE INVENTION [0003] Fiberglass insulation products generally consist of glass fibers bonded together by a polymeric binder. An aqueous polymer binder is sprayed onto matted glass fibers soon after they have been formed, and while they are still hot. The polymer binder tends to accumulate at the junctions where fibers cross each other, holding the fibers together at these points. The heat from the fibers causes most of the water in the binder to vaporize. An important property of the fiberglass binder is that it must be flexible--allowing the fiberglass product to be compressed for packaging and shipping but recover to its full vertical dimension when installed. [0004] Phenol-formaldehyde binders have been the primary binders in the manufacture of fiberglass insulation. These binders are low-cost and easy to apply and readily cured. They provide a strong bond, yet elasticity and good thickness recovery to obtain the full insulating value. One drawback to phenol-formaldehyde binders is that they release significant levels of formaldehyde into the environment during manufacture. The cured resin can also release formaldehyde in use, especially when exposed to acidic conditions. Exposure to formaldehyde produces adverse health effects in animals and humans. Recent developments have lead to reduced emissions of formaldehyde, as in U.S. Pat. No. 5,670,585, or as in a mixture of phenol formaldehyde binders with carboxylic acid polymer binders, as in U.S. Pat. No. 6,194,512, however formaldehyde emissions remain a concern. [0005] Alternative chemistries have been developed to provide formaldehyde-free binder systems. These systems involve three parts: (1) a polymer, such as a polycarboxyl, polyacid, polyacrylic, or anhydride; (2) a cross-linker that is an active hydrogen compound such as trihydric alcohol (U.S. Pat. No. 5,763,524; U.S. Pat. No. 5,318,990), triethanolamine (U.S. Pat. No. 6,331,350; EP 0990728), beta-hydroxy alkyl amides (U.S. Pat. No. 5,340,868; or hydroxy alkyl urea (U.S. Pat. Nos. 5,840,822; 6,140,388) and (3) a catalyst or accelerator such as a phosphorous containing compound or a fluoroborate compound (U.S. Pat. No. 5,977,232). [0006] These alternative binder composition work well, however, there is a need for alternative fiberglass binder systems that provide the performance advantages of phenol-formaldehyde resins, in a formaldehyde-free system. [0007] Surprisingly it has been found that a polymeric binder having both acid and hydroxyl or amine groups produces a strong, yet flexible and clear fiberglass insulation binder system. The presence of both the acid and active hydrogen functionalities within the same copolymer eliminates the need for an extra component, and also places the functional groups in close proximity for efficient crosslinking. SUMMARY OF THE INVENTION [0008] The present invention is directed to a nonwoven binder composition, having an aqueous solution comprising a copolymer binder having both an acid functionality and hydroxyl or amine functionality. [0009] The invention is also directed to a bonded fiberglass mat having directly deposited thereon a copolymer binder having both an acid and hydroxyl or amine functionality. DETAILED DESCRIPTION OF THE INVENTION [0010] The present invention relates to a non-woven binder composition containing a copolymer binder synthesized from at least one acid-functional monomer, and at least one hydroxyl or amine functional monomer. [0011] The copolymer binder is synthesized from one or more acid monomers. The acid monomer may be a carboxylic acid monomer, a sulfonic acid monomer, a phosphonic acid monomer, or a mixture thereof. The acid monomer makes up from 1 to 99 mole percent, preferably from 50 to 95 mole percent, and most preferably from 60 to 90 mole percent of the polymer. In one preferred embodiment, the acid monomer is one or more carboxylic acid monomers. The carboxylic acid monomer includes anhydrides that will form carboxyl groups in situ. Examples of carboxylic acid monomers useful in forming the copolymer of the invention include, but are not limited to acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, fumaric acid, maleic acid, cinnamic acid, 2-methylmaleic acid, itaconic acid, 2-methylitaconic acid, sorbic acid, alpha-beta-methylene glutaric acid, maleic anhydride, itaconic anhydride, acrylic anhydride, methacrylic anhydride. Preferred monomers are maleic acid, acrylic acid and methacrylic acid. The carboxyl groups could also be formed in situ, such as in the case of isopropyl esters of acrylates and methacrylates that will form acids by hydrolysis of the esters when the isopropyl group leaves. [0012] Examples of phosphonic acid monomers useful in forming the copolymer include, but are not limited to, vinyl phosphonic acid. [0013] Examples of sulfonic acid monomers useful in forming the copolymer include, but are not limited to, styrene sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, vinyl sulfonic acid, methallyl sulfonic acid, sulfonated styrene, and allyloxybenzene sulfonic acid. [0014] The copolymer binder is also synthesized from one or more hydroxyl- or amine-containing monomers. The hydroxyl or amine monomer makes up from I to 75 mole percent, and preferably 10 to 20 mole percent of the copolymer. Examples of hydroxyl monomers useful in forming the copolymer of the invention include, but are not limited to, hydroxy propyl (meth) acrylate, hydroxy ethyl (meth) acrylate, hydroxy butyl (meth) acrylate and methacrylate esters of poly(ethylene/propylene/butylene) glycol. In addition, one could use the acrylamide or methacrylamide version of these monomers. Also, monomers like vinyl acetate that can be hydrolyzed to vinyl alcohol after polymerization may be used. Preferred monomers are hydroxypropyl acrylate and methacrylate. Examples of amine-functional monomers useful in the present invention include, N,N-dialkyl aminoalkyl (meth)acrylate, N,N-dialkyl aminoalkyl (meth) acrylamide, namely, dimethyl aminopropyl methacrylate, dimethyl aminoethyl methacrylate, tert-butyl aminoethyl methacrylate and dimethyl aminopropyl methacrylamide. In addition, monomers like vinyl formamide and vinyl acetamide that can be hydrolyzed to vinyl amine after polymerization may also be used. Furthermore, aromatic amine monomers such as vinyl pyridine may also be used. The copolymer could contain a mixture of both hydroxyl and amine functional monomers. It was found that copolymers containing lower levels of these functional monomers were more flexible than copolymers containing higher levels of these functional monomers. While not being bound to any particular theory, it is believed this may be related to the lower T.sub.g copolymers that are formed. Amide-functional monomers could also be used to form the copolymer if a higher cure temperature is used in forming the finished non-woven. [0015] The mole ratio of acid-functional monomer to hydroxyl- or amine-functional monomer is preferably from 100:1 to 1:1, and more preferably from 5:1 to 1.5:1. [0016] Other ethylenically unsaturated monomers may also be used to form the copolymer binder, at a level of up to 50 mole percent based on the total monomer. These monomers can be used to obtain desirable properties of the copolymer, in ways known in the art. For example, hydrophobic monomers can be used to increase the water-resistance of the non-woven. Monomers can also be use to adjust the Tg of the copolymer to meet the end-use application requirements. Useful monomers include, but are not limited to, (meth)acrylates, maleates, (meth)acrylamides, vinyl esters, itaconates, styrenics, acrylonitrile, nitrogen functional monomers, vinyl esters, alcohol functional monomers, and unsaturated hydrocarbons. Low levels of up to a few percent of crosslinking monomers may also be used to form the polymer. The extra crosslinking improves the strength of the bonding, yet at higher levels would be detrimental to the flexibility of the resultant material. The crosslinking moieties can be latent crosslinking where the crosslinking reaction takes place not during polymerization but during curing of the binder. Chain-transfer agent may also be used, as known in the art, in order to regulate chain length and molecular weight. The chain transfer agents may be multifunctional so as to produce star type polymers. [0017] The copolymer is synthesized by known methods of polymerization, including solution, emulsion, suspension and inverse emulsion polymerization methods. In one preferred embodiment, the polymer is formed by solution polymerization in an aqueous medium. The aqueous medium may be water, or a mixed water/water-miscible solvent system, such as a water/alcohol solution. The polymerization may be batch, semi-batch, or continuous. The polymers are typically prepared by free radical polymerization but condensation polymerization may also be used to produce a polymer containing the desired moieties. For example, copolymers of poly(aspartate-co-succinimide) can be prepared by condensation polymerization. This copolymer can be further derivatized by alkanolamines to produce a polymer with carboxylic acid as well as hydroxyl moieties. The monomers may be added to the initial charge, added on a delayed basis, or a combination. The copolymer is generally formed at a solids level in the range of 15 to 60 percent, and preferably from 25 to 50 percent, and will have a pH in the range of from 1-5, and preferably from 2-4. One reason a pH of above 2 is preferred is for the hazard classification it will be afforded. The copolymer may be partially neutralized, commonly with sodium, potassium, or ammonium hydroxides. The choice of base, and the partial-salt formed will affect the T.sub.g of the copolymer. The use of calcium or magnesium base for neutralization produces partial salts having unique solubility characteristics, making them quite useful depending on end-use application. [0018] The copolymer binder may be random, block, star, or other known polymer architecture. Random polymers are preferred due to the economic advantages; however other architectures could be useful in certain end-uses. Copolymers useful as fiberglass binders will have weight average molecular weights in the range of 1,000 to 300,000, and preferably in the range of 2,000 to 15,000. The molecular weight of the copolymer is preferably in the range of 2,500 to 10,000, and most preferably from 3,000 to 6,000. [0019] The copolymer binder will form strong bonding without the need for a catalyst or accelerator. One advantage of not using a catalyst in the binder composition is that catalysts tend to produce films that can discolor, or films that release phosphorous-containing vapors. The copolymer of the present invention, used without a catalyst, forms a clear film. An accelerator or catalyst may preferentially be combined with the copolymer binder in order to decrease the time for cure, increase the crosslinking density, reduce the curing time, and/or decrease the water sensitivity of the cured binder. Catalysts useful with the binder are those known in the art including, but not limited to, alkali metal salts of a phosphorous-containing organic acid, such as sodium hypophosphate, sodium phosphite, potassium phosphite, disodium pyrophosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, sodium hexametaphosphate, potassium polyphosphate, potassium tripolyphospate, sodium trimetaphosphate, sodium tertametaphosphate; fluouroborates, and mixtures thereof. The catalyst could also be a Lewis acid, such as magnesium citrate or magnesium chloride; a Lewis base; or a free radical generator, such as a peroxide. The catalyst is present in the binder formulation at from 0 to 25 percent by weight, and more preferably from 1 to 10 percent by weight based on the copolymer binder. Continue reading... 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