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10/22/09 - USPTO Class 423 |  13 views | #20090263309 | Prev - Next | About this Page  423 rss/xml feed  monitor keywords

Shear reactor for vortex synthesis of nanotubes

USPTO Application #: 20090263309
Title: Shear reactor for vortex synthesis of nanotubes
Abstract: Continuous nanotube synthesis by vortex deposition occurs in an axially-fed shear reactor comprising coaxial counter-rotating disk impeller/electrodes charged as anodes. Nanotube evolving ends, charged as cathodes, point toward the anode axis of rotation and protrude into the space between the anodes. Radial vortices in a shear layer of the space, between the boundary layers on the impeller/electrodes, spin cations to be deposited on evolving nanotube ends approximately at the vortex axis, so deposition is by swirling cathode fall. The evolved nanotubes are extracted mechanically, and they conduct electrons from charging means to charge the evolving ends as cathodes. The preferential synthesis of metallic carbon nanotubes is due to the greater resistance of non-metallic structures such as graphite or semiconductive structures. Ozone serves to oxidize non-metallic structures and to functionalize the loose ends of nanotube fragments. Dopants can be added to the evolving nanotubes by introduction of dopants at the periphery because the evolving ends are maintained in stable locations. Or dopants can be added by the simultaneous decomposition of gases (for example, carbon dioxide and nitrogen gas) within the reactor or in an external reactor. (end of abstract)



Agent: Marger Johnson & Mccollom, P.C. - Portland, OR, US
Inventors: David J. McCutchen, Wilmot H. McCutchen
USPTO Applicaton #: 20090263309 - Class: 4234471 (USPTO)

Shear reactor for vortex synthesis of nanotubes description/claims


The Patent Description & Claims data below is from USPTO Patent Application 20090263309, Shear reactor for vortex synthesis of nanotubes.

Brief Patent Description - Full Patent Description - Patent Application Claims
  monitor keywords APPLICATION HISTORY

The applicants claim the benefit of provisional application 61/026,963 entitled “Continuous Synthesis of Carbon Nanotubes by Vortex Turbulence” filed Feb. 7, 2008 by Wilmot H. McCutchen and David J. McCutchen, as well as provisional application 61/034,242 entitled “Dual Disk Dynamo High Shear Reactor” by Wilmot H. McCutchen and David J. McCutchen, filed Mar. 6, 2008.

FIELD OF THE INVENTION

This invention applies to the synthesis of carbon or other nanotubes and to electrolysis in turbulent reactors.

BACKGROUND OF THE INVENTION

Nanotubes have been synthesized from many materials, including boron nitride, tungsten disulfide, titanium dioxide, molybdenum disulfide, bismuth, copper, and gold.

Carbon nanotubes in particular are a commercially valuable form of carbon that has many remarkable properties. The fibers are 100 times stronger in tensile strength than steel, and are the most efficient heat conductors known. These nanotubes have a high degree of stiffness, due to their molecular structure. They can theoretically be formed in any length, but present methods of formation include a random direction of formation, and this limits the resulting length the nanotube to a couple of centimeters as best.

Chemical vapor deposition is a method currently used by commercial companies creating quantities of nanotubes. The formation of the nanotubes is made from the evaporation of a solution of carbon or other ions suspended in alcohol or another solvent. This makes the tubes form in random directions to a length of at most a few millimeters. The solvent with the forming tubes can be in the form of an aerogel, and the final step of deposition can be as the aerogel is being drawn into a cable. This can achieve speeds of deposition of up to 2 meters a minute, but the cable is a grouping of short nanotube lengths, and lacks the tensile strength that would come from a single long nanotube.

Laser ablation and arc discharge are other synthesis methods. In laser ablation for carbon nanotubes, a high energy laser vaporizes a carbonaceous target to produces carbon ions, whereas arc discharge vaporizes carbon electrodes. Isotropic turbulence spins some of these carbon ions into nanotubes, which are very short in length due to the chaotic orientation and short duration of any formation vortices.

Depending on their structure, carbon nanotubes can be electrical superconductors, also known as metallic nanotubes, or semiconductors. Conventional synthesis methods produce a mixture of conductive and semiconductor nanotubes, which must later be separated by suitable means outside of the reactor.

SUMMARY AND OBJECTS AND ADVANTAGES OF THE PRESENT INVENTION

The present invention represents a scalable approach to continuous synthesis of long nanotubes. A flow of carbon ions is organized into radial vortices which feed the formation of continuously evolving nanotubes. The ion vortices are mechanically forced by counter-rotating disk impeller/electrodes, and the vortices create a solenoidal magnetic field which causes self-tightening of the vortex. Turbulence is anisotropic, or directionally oriented, instead of the random isotropic turbulence of conventional reactors, so the vortices are coherent and radially arranged. The formation process within these vortices favors the creation of longer strands that can be spooled up to an external reel continuously. This can make the production of long nanotube strands in large quantities a commercial reality.

Another advantage is that the formation process tends to favor the production of metallic instead of semiconducting nanotubes. The evolving nanotubes are charged as cathodes, and the current will flow easily through the metallic nanotubes to their evolving ends, but does not flow easily through semiconductive nanotubes due to their higher resistance. Therefore semiconductive nanotubes tend not to evolve because their evolving ends are starved of electrons by their resistance.

A further advantage is the production of doped nanotubes with variations along their length, produced by changing the conditions in which the evolving end of the nanotube is formed.

The ion source may be electrolysis within the shear reactor, or an external source. In the case of an external source, the source gas fed into the shear reactor is a mixture of a carrier gas and the ions which will be rolled into nanotubes by coherent directed turbulence and swirling cathode fall. The nanotubes could therefore be of gold or other conventional nanotube materials, as well as of carbon.

DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross section of one half of the preferred embodiment of the vortex synthesis shear reactor of the present invention.

FIG. 2 is a cross section close-up of the area of the formation zone.



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