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02/26/09 - USPTO Class 525 |  24 views | #20090054594 | Prev - Next | About this Page  525 rss/xml feed  monitor keywords

Fluoropolymer low reflecting layers for plastic lenses and devices

USPTO Application #: 20090054594
Title: Fluoropolymer low reflecting layers for plastic lenses and devices
Abstract: A one or two layer coating system has been developed for plastic substrates. The one coating system low reflective layer consists of a fluorinated copolymer having the formula: VF2/TFE/HFP, VF2/HFP or VF2/TFE/PMVE. In the two coating system, the upper coating layer consists of TFE/HFP, VF2/TFE/HFP, or TFE/Perfluorodioxole, and the lower coating layer consists of VF2/TFE/HFP, VF/TFE/HFP, VAc/TFE/HFIB, or TFE graft to PVOH. (end of abstract)



Agent: E I Du Pont De Nemours And Company Legal Patent Records Center - Wilmington, DE, US
Inventors: ANDREW EDWARD FEIRING, TATSUHIRO TAKAHASHI, MUREO KAKU, RONALD EARL USCHOLD, ROBERT CLAYTON WHELAND, SAWATO IWATO
USPTO Applicaton #: 20090054594 - Class: 525199 (USPTO)

Fluoropolymer low reflecting layers for plastic lenses and devices description/claims


The Patent Description & Claims data below is from USPTO Patent Application 20090054594, Fluoropolymer low reflecting layers for plastic lenses and devices.

Brief Patent Description - Full Patent Description - Patent Application Claims
  monitor keywords FIELD OF INVENTION

The present invention relates to fluoropolymer coated plastics. More specifically, it relates to fluoropolymer coated plastics having good adhesion, low reflective properties, and water and oil repellency.

TECHNICAL BACKGROUND

Much work has been done concerning low reflective plastics, particularly for plastic lenses and optical devices. One method used is vapor disposition of oxidized metal on the surface of the plastic. However, this method uses a batch process and when the substrate is large, the productivity becomes low. Another way is to apply a coating of fluoropolymer solutions. The coating is done by a dipping process and is applicable for large substrates with high productivity. Though fluoropolymers have low reflective indexes, they also have very poor adhesion with plastic substrates. Improvement in the adhesion between fluoropolymers and substrate plastics has been long sought. The purpose of this invention is to provide the technology for low reflective index and good adhesion using fluoropolymer solutions.

SUMMARY OF THE INVENTION

The one layer coating system provided by the present invention consists of a fluorinated copolymer having the formula:

VF2/TFE/HFP

wherein the molar ratio of Tetrafluoroethylene (TFE) to Hexafluoropropylene (HFP) is between 0.1 and 1.9, and the VF2 content is 12 to 60 mole %. Preferably the VF2 content is 12 to 50 mole % for PMMA substrates and 18 to 50 mole % for PC, PET, and PS substrates. More preferred is where the molar ratio of TFE to HFP is between 0.9 and 1.9, and the VF2 content is preferably 12 to 50 mole % for Polymethylmethacrylate (PMMA) substrates and 18 to 50 mole % for Polycarbonate (PC), Polyethyleneterephthalate (PET), and Polysulfone (PS) substrates.

Also preferred is where the VF2 content is greater than 50 mole % to 60 mole %; more preferred is where the substrate is PMMA, PC, PET or glass.

A one layer coating system is also provided by the present invention comprising a fluorinated copolymer having the formula

VF2/HFP

wherein the VF2 content is about 40-80 mole %. Preferably, the VF2 content is about 40-50 mole % and the substrate is PMMA. Also preferably, the VF2 content is about 70-80 mole % and the substrate is glass.

A one layer coating system is also provided by the present invention comprising a fluorinated copolymer having the formula

VF2/TFE/PMVE



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Brief Patent Description - Full Patent Description - Patent Application Claims

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Previous Patent Application:
Fluoroelastomer composition and molded fluororubber article
Next Patent Application:
Compounding formulations for producing articles from guayule natural rubber
Industry Class:
Synthetic resins or natural rubbers -- part of the class 520 series

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